Kinetics of phase transition in a lyotropic liquid-crystalline polymer system

Citation
T. Sato et T. Shimizu, Kinetics of phase transition in a lyotropic liquid-crystalline polymer system, MOLEC CRYST, 365, 2001, pp. 1343-1351
Citations number
17
Categorie Soggetti
Physical Chemistry/Chemical Physics
Volume
365
Year of publication
2001
Pages
1343 - 1351
Database
ISI
SICI code
Abstract
The radius R, the radius distribution function, and the number density of g rowing cholesteric droplets in metastable solutions' of cellulose tris-(phe nyl carbamate) (CTC) were measured as function of time t after quench, by p olarizing microscopy. From the R dependence of the growth rate of cholester ic droplets, we concluded that the rate-determining process in the choleste ric droplet growth is the orientation of CTC molecules at the isotropic-cho lesteric interface.