Equilibrium size and textures of islands in free-standing smectic C* films

Citation
Rb. Meyer et al., Equilibrium size and textures of islands in free-standing smectic C* films, MOLEC CRYST, 364, 2001, pp. 123-131
Citations number
5
Categorie Soggetti
Physical Chemistry/Chemical Physics
Volume
364
Year of publication
2001
Pages
123 - 131
Database
ISI
SICI code
Abstract
In free standing films of one smectic C* material, Chisso 1015, we observe circular islands, of greater thickness than the background film. These isla nds, nucleated by smoke particles, grow to an equilibrium diameter that is a function of their thickness. We present data on island size, and a theory attributing the finite equilibrium size to a negative island edge energy a rising from a spontaneous bend term in the elastic free energy for the isla nds. We also observe textural transformations within the islands, attribute d to a difference between splay and bend elastic constants, combined with w eak anchoring of the director at a point disclination at the center of an i sland.