Application of hygrothermally decomposed polyurethane in rubber recipes Part 2 - Influence of hygrothermally decomposed polyester-urethane on cure characteristics and viscoelastic behaviour of styrene/butadiene rubber
A. Mousa et J. Karger-kocsis, Application of hygrothermally decomposed polyurethane in rubber recipes Part 2 - Influence of hygrothermally decomposed polyester-urethane on cure characteristics and viscoelastic behaviour of styrene/butadiene rubber, PLAS RUB C, 30(7), 2001, pp. 309-313
Hygrothermally decomposed polyester-urethane (HD PUR) was mixed at concentr
ations up to 20 pphr with a styrene/butadiene rubber (SBR), using an effici
ent vulcanisation system. Changes in the cure behaviour were followed by vu
lcametry, plate-plate rheometry, and differential scanning calorimetry. It
was found that the degree of crosslinking was increased by the incorporatio
n of HD PUR, which acts as an accelerator in SBR stocks. Increasing crossli
nking resulted in higher stiffness and strength and was accompanied by a re
duction in elongation at break and swelling index. (C) 2001 IoM Communicati
ons Ltd.