Thermal isomerization of 2-bromo-2-fluoro-1-alkylidenecyclopropanes in polar solvents

Authors
Molchanov, AP Kostikov, RR
Citation
Ap. Molchanov et Rr. Kostikov, Thermal isomerization of 2-bromo-2-fluoro-1-alkylidenecyclopropanes in polar solvents, RUSS J ORG, 37(6), 2001, pp. 784-786
Citations number
3
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY
ISSN journal
10704280 → ACNP
Volume
37
Issue
6
Year of publication
2001
Pages
784 - 786
Database
ISI
SICI code
1070-4280(200106)37:6<784:TIO2IP>2.0.ZU;2-T
Abstract
2-Bromo-2-fluoro-1-alkylidenecyclopropanes heated in polar solvents undergo isomerization into substituted 3-bromo-2-fluoro-1,3-butadienes. 2-Bromo-3- methyl-1-methylene-3-phenyl-2-fluorocyclopropane at heating afforded a mixt ure of substituted 1-(bromofluoromethylene)cyclopropane and isomeric 1-brom o-1-fluoro-1,3-butadienes.