Dialkyl peroxides decomposition in the presence of quaternary ammonium halides

Authors
Maksyuta, NV Suprun, VY Opeida, IA Turovskii, NA
Citation
Nv. Maksyuta et al., Dialkyl peroxides decomposition in the presence of quaternary ammonium halides, RUSS J ORG, 37(6), 2001, pp. 814-818
Citations number
15
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY
ISSN journal
10704280 → ACNP
Volume
37
Issue
6
Year of publication
2001
Pages
814 - 818
Database
ISI
SICI code
1070-4280(200106)37:6<814:DPDITP>2.0.ZU;2-X
Abstract
Decomposition of dicumyl peroxide and cumyl tert-butyl peroxide was studied in the presence of tetraethylammonium halides in acetonitrile, dimethylfor mamide, 2-propanol, and acetic acid. The tetraethylammonium halides acceler ate the decomposition of dialkyl peroxides in 2-propanol and acetic acid, b ut do not affect the reaction velocity in dimethylformamide and acetonitril e. The decomposition products character depends on the solvent nature.