Effects of discharge on silver loading and transport in the Quinnipiac River, Connecticut

Silver concentrations were measured in water and sediment samples collected from the Quinnipiac River in Connecticut. This river was chosen for study because of its history of industrialization and high levels of Ag contamina tion. Sewage treatment plant (STP) effluent accounts for similar to 15% of the total river discharge and similar to 60%, of the dissolved Ag in the wa ter column during baseflow conditions. Erosion of contaminated riverbank se diment is the primary source of particulate Ag in the river. Both dissolved and particulate Ag fractions vary as a function of river discharge. Increa sed discharge due to rain events decreases the relative importance of STP e ffluent, and thus dilutes the dissolved Ag concentration in the water colum n. Conversely, increasing discharge results in higher particulate Ag concen trations from increased erosion. The results of this study clearly indicate that both point and non-point sources contribute significantly to Ag loadi ng in this river system, with the level of river discharge determining the relative importance of each. (C) 2001 Elsevier Science B.V. All rights rese rved.