The effect of grain size of SnO2 was examined on the sensitivities of SnO2
thick films to odoriferous and odorless gases. The sensitivity to odors and
the odor selectivity to odorless gases depended strongly on the grain size
, and the optimum mean grain size of SnO2 for odor sensing was about 176 nm
observed by SEM. The odor selectivity to odorless gases was further improv
ed by adding PbOx to the SnO2 thick films. By coating the original PbOx-add
ed SnO2 thick films with various metal oxide catalytic layers, the sensing
elements became characterized by the peculiar odor selectivities. An odor i
dentification system has been developed utilizing the SnO2-based sensor arr
ay composed of the original thick film and seven sensing elements with diff
erent metal oxide catalytic layers, and pattern recognition technique. Odor
s of a similar nature from citrus fruit oils of grapefruit, sweet orange, l
emon, bergamot and petit grain. and aromas of ground coffee beans produced
in different countries were identified by principal component analysis (PCA
). (C) 2001 Elsevier Science B.V. All rights reserved.