Hy. Lee et al., THE INFLUENCE OF CYCLIC TREATMENTS WITH H2O2 AND HF SOLUTIONS ON THE ROUGHNESS OF SILICON SURFACE, Bulletin of the Korean Chemical Society, 18(7), 1997, pp. 737-740
The influence of cyclic treatments with H2O2/DIW (1:10) and HF/DIW (1:
100) on the roughness of silicon surface in the wet chemical processin
g was investigated by atomic force microscopy (AFM). During the step o
f the SC-1 cleaning, there is a large increase in roughness on the sil
icon surface which will result in the poor gate oxide breakdown proper
ties. The roughness of the silicon wafer after the SC-1 cleaning step
was reduced by cyclic treatments of hydrogen peroxide solution and hyd
rofluoric acid solution instead of HF-only cleaning. AFM images after
each step clearly illustrated that the average roughness of silicon su
rface after three times treatments with H2O2 and HF solutions was redu
ced by 10 times compared with that after the SC-1 cleaning step.