A. Benjelloun et al., USE OF FLUORESCENT-PROBES (PYRENE AND MOLECULAR ROTOR) FOR THE DETECTION OF HYDROPHOBIC MICRODOMAINS IN AMPHIPHILIC POLYMERS AQUEOUS-SOLUTIONS, Macromolecular symposia, 119, 1997, pp. 283-290
The purpose of the present investigation deals with a comparative stud
y between the magnitudes of the local viscosity and/or the polarity of
the hydrophobic microdomains generated by poly (3-hexadecyl-1-vinylim
idazolium bromide) in an aqueous medium using a cinnamylidene molecula
r rotor and pyrene as fluorescent probes. Moreover, the results are co
mpared with the data obtained with micelles of conventional surfactant
s such as the homopolymer repetitive unit model and CTAB.