Tensile experiments have established that polycrystals of stoichiometr
ic Ni3Al are brittle in air over the range of strain rate from 10(-4)
to 7 s(-1). Ni-rich polycrystals and boron-doped stoichiometric alloys
undergo a brittle-to-ductile transition upon increasing strain rate.
The transition correlates with the enrichment of nickel on the grain b
oundaries. The strain rate and (presumably) environmental effect appea
r to be caused by the embrittlement not of the Ni3Al per se, but of th
e intergranulular Ni-enriched region. (C) 1997 Acta Metallurgica Inc.