We use scanning gate microscopy to precisely locate the gating response in
field-effect transistors (FETs) made from semiconducting single-wall carbon
nanotubes. A dramatic increase in transport current occurs when the device
is electrostatically doped with holes near the positively biased electrode
. We ascribe this behavior to the turn-on of a reverse biased Schottky barr
ier at the interface between the p-doped nanotube and the electrode. By pos
itioning the gate near one of the contacts, we convert the nanotube FET int
o a rectifying nanotube diode. These experiments both clarify a longstandin
g debate over the gating mechanism for nanotube FETs and indicate a strateg
y for diode fabrication based on controlled placement of acceptor impuritie
s near a contact. (C) 2001 American Institute of Physics.