On the promotion of Ag/gamma-Al2O3 by Cs for the SCR of NO by C3H6

Citation
Ih. Son et al., On the promotion of Ag/gamma-Al2O3 by Cs for the SCR of NO by C3H6, CATAL LETT, 75(3-4), 2001, pp. 191-197
Citations number
38
Categorie Soggetti
Physical Chemistry/Chemical Physics","Chemical Engineering
Journal title
CATALYSIS LETTERS
ISSN journal
1011372X → ACNP
Volume
75
Issue
3-4
Year of publication
2001
Pages
191 - 197
Database
ISI
SICI code
1011-372X(2001)75:3-4<191:OTPOAB>2.0.ZU;2-N
Abstract
The promotion of Ag/gamma -Al2O3 by adding alkali metals (Li, Na, K, Cs) fo r selective catalytic reduction of NO with C3H6 was studied in this work. T he activity of NO reduction was enhanced by addition of Cs to Ag/gamma -Al2 O3 in the presence of excess oxygen and SO2. The stability and growth of si lver oxide particles were promoted and the dispersion of silver particles o n gamma -Al2O3 was improved by the addition of 0.5 wt% Cs and 1 wt% Cs to 2 wt% Ag/gamma -Al2O3, respectively. The results were confirmed by H-2 TPR, UV-Vis DRS, TEM, and XPS.