Inverse gas chromatography study of acid-base properties of cation resins used as catalysts of Bisphenol A synthesis

Citation
M. Bialon et al., Inverse gas chromatography study of acid-base properties of cation resins used as catalysts of Bisphenol A synthesis, CHEM ANAL, 46(5), 2001, pp. 647-652
Citations number
7
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences
Journal title
CHEMIA ANALITYCZNA
ISSN journal
00092223 → ACNP
Volume
46
Issue
5
Year of publication
2001
Pages
647 - 652
Database
ISI
SICI code
0009-2223(2001)46:5<647:IGCSOA>2.0.ZU;2-B
Abstract
The inverse gas chromatography method have been used for estimation of the relative number of acid and base active centres for two types of cation exc hangers that are used as catalysts of Bisphenol A industrial synthesis. It was stated that after a few weeks of the continuous work of reactors filled with the catalysts, the acid base properties of the latter have under.-one significant changes. The number or acid centres decreased while the number of base mitres increased. Simultaneously, the decrease of the yield of the synthesis product was observed.