M. Gruselle et al., Optically active molecule-based magnets: Enantioselective self-assembling,optical, and magnetic properties, CHIRALITY, 13(10), 2001, pp. 712-714
In, this short communication we describe the synthesis and the optical and
magnetic properties of optically active three dimensional (3D) bimetallic [
Cr-Mn] networks {[Delta Cr(III)Delta Mn-II(ox)(3)][Delta Ru-II(bpy)(3)]ClO4
}(n)1 - Delta, {[Lambda Cr(III)Lambda Mn-II(ox)(3)][Lambda Ru-II (bpy)(3)]C
lO4}(n) 1 - Lambda and {[Delta Cr(III)Delta Mn-II(ox)(3)][Delta Ru-II (bpy)
(2)p p y]}(n) 2 - Delta, {[Delta Cr(III)Delta Mn-II(ox)(3)][Delta Ru-II (bp
y)(2)ppy]}(n) 2 - Lambda (ox = oxalate, bpy = bipyridine, ppy = phenyl-pyri
dine). (C) 2000 Wiley-Liss, Inc.