Preparation and characterization of a new solvent-free polymer electrolytebased on spiroketal structure

Authors
Tsutsumi, H Shirotani, R Onimura, K Oishi, T
Citation
H. Tsutsumi et al., Preparation and characterization of a new solvent-free polymer electrolytebased on spiroketal structure, EL SOLID ST, 4(12), 2001, pp. A195-A196
Citations number
8
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ELECTROCHEMICAL AND SOLID STATE LETTERS
ISSN journal
10990062 → ACNP
Volume
4
Issue
12
Year of publication
2001
Pages
A195 - A196
Database
ISI
SICI code
1099-0062(200112)4:12<A195:PACOAN>2.0.ZU;2-6
Abstract
Solvent-free solid polymer electrolytes based on spiropolymers were prepare d and their properties were confirmed by conductance, differential scanning calorimetry, and X-ray diffraction measurements. The spiropolymer was synt hesized from the bicyclic diketone and pentaerythritol. The spiro-polyketal (SP) dissolves lithium perchlorate and the conductivity of the (SP) 1.5(Li ClO4)1 complex is 4.24 x 10(-5) S cm(-1) at 30 degreesC and 3.83 x 10(-4) S cm(-1) at 60 degreesC. (C) 2001 The Electrochemical Society.