We have made polyvinylalcohol membranes containing mordenite which have twe
nty times better selectivity for protons over methanol than perfluorinated
sulfonic acid polymers. Membranes like these should improve the efficiencie
s of fuel cells fed directly with methanol. Our results show that further i
mprovements are possible with composite membranes, but that these improveme
nts will require polymers less conductive than those currently used. This i
s the opposite of conventional wisdom. (C) 2001 The Electrochemical Society
.