Density dependence of mean kinetic energy in liquid and solid hydrogen at 19.3 K

Citation
M. Zoppi et al., Density dependence of mean kinetic energy in liquid and solid hydrogen at 19.3 K, EUR PHY J B, 23(2), 2001, pp. 171-178
Citations number
41
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
EUROPEAN PHYSICAL JOURNAL B
ISSN journal
14346028 → ACNP
Volume
23
Issue
2
Year of publication
2001
Pages
171 - 178
Database
ISI
SICI code
1434-6028(200109)23:2<171:DDOMKE>2.0.ZU;2-V
Abstract
We have measured, using the TOSCA spectrometer at ISIS, the inelastic incoh erent neutron scattering spectrum of liquid and solid para-hydrogen along t he T = 19.3 K isotherm. From the high-energy region of the spectrum, where the Impulse Approximation for the Centre of Mass motion applies, we have be en able to extract the mean translational kinetic energy, which, as expecte d, turns out rather different from the classical value and density dependen t. We find that the density behaviours in the liquid and the solid phase ar e slightly different. This confirms a similar feature already observed ill liquid and solid helium at T = 6.1 K [M. Celli, Al. Zoppi, J. Mayers, Phys. Rev. B 58, 242 (1998)]. The spectra from the solid phase have been also an alysed in the low-energy region and allowed us to derive the Debye-Waller f actor of solid para-hydrogen as a function of density. The comparison with the available experimental data in the literature is rather good and confir ms the excellent performances of TOSCA in the spectroscopic analysis of the condensed phases of para-hydrogen.