F. Despa et Rs. Berry, Relaxation dynamics in the presence of unequally spaced attractors along the reaction coordinate, EUR PHY J D, 16(1-3), 2001, pp. 55-58
We show how reaction coordinate path lengths affect the relaxation efficien
cy of a complex system. To this purpose, we consider the metric contributio
ns to the transition rates. These metric contributions contain information
about the system's change of geometry at the barrier crossing and, therefor
e, are directly related, differentially, to the path lengths. The results o
f this work can enrich the accuracy with which we describe how complex syst
ems relax to preferential structures.