Relaxation dynamics in the presence of unequally spaced attractors along the reaction coordinate

Citation
F. Despa et Rs. Berry, Relaxation dynamics in the presence of unequally spaced attractors along the reaction coordinate, EUR PHY J D, 16(1-3), 2001, pp. 55-58
Citations number
16
Categorie Soggetti
Physics
Journal title
EUROPEAN PHYSICAL JOURNAL D
ISSN journal
14346060 → ACNP
Volume
16
Issue
1-3
Year of publication
2001
Pages
55 - 58
Database
ISI
SICI code
1434-6060(200109)16:1-3<55:RDITPO>2.0.ZU;2-U
Abstract
We show how reaction coordinate path lengths affect the relaxation efficien cy of a complex system. To this purpose, we consider the metric contributio ns to the transition rates. These metric contributions contain information about the system's change of geometry at the barrier crossing and, therefor e, are directly related, differentially, to the path lengths. The results o f this work can enrich the accuracy with which we describe how complex syst ems relax to preferential structures.