Microwave and BF3 promoted rearrangement of allyloxycoumarins to allylcoumarins and dihydrofurocoumarins

Citation
Mr. Saidi et F. Rajabi, Microwave and BF3 promoted rearrangement of allyloxycoumarins to allylcoumarins and dihydrofurocoumarins, HETEROCYCLE, 55(9), 2001, pp. 1805
Citations number
27
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
HETEROCYCLES
ISSN journal
03855414 → ACNP
Volume
55
Issue
9
Year of publication
2001
Database
ISI
SICI code
0385-5414(20010901)55:9<1805:MABPRO>2.0.ZU;2-H
Abstract
Allyl, crotyl, methallyl and cinamyl ethers of 4-hydroxy-, 7-hydroxy-, and 4-methyl-7-hydroxycoumarins have been efficiently synthesized and rearrange d to substituted allylcoumarins under microwave irradiation. Irradiation of allylcoumarins in the presence of BF3/ether directly produced substituted dihydrofurocoumarins in good yields.