S. Nakayama, LaFeO3 perovskite-type oxide prepared by oxide-mixing, co-precipitation and complex synthesis methods, J MATER SCI, 36(23), 2001, pp. 5643-5648
The perovskite oxide, LaFeO3, was synthesized by three different preparatio
n methods i.e., the calcination of a mixture of La2O3 and Fe2O3 (La-Fe-O),
a co-precipitated precursor (La-Fe-OH), La(OH)(3) and Fe(OH)(3), and a hete
ronuclear complex (La-Fe-CN), La[Fe(CN)(6)] . 5H(2)O. The obtained powders
were characterized by thermogravimetric analysis, powder X-ray diffraction,
electron microprobe analysis, specific surface area measurement and scanni
ng electron microscopy. The formation of LaFeO3 is clearly recognized for L
a-Fe-O, La-Fe-OH and La-Fe-CN at calcining temperatures above 1000, 800 and
600 degreesC, respectively. The mean particle diameter of La-Fe-CN calcine
d at 600 degreesC for 2 hours was 30 nm. The LaFeO3 perovskite oxide powder
obtained by the thermal decomposition of La-Fe-CN was most uniform on an a
tomic level and the nanosized LaFeO3 powder was obtained at low temperature
s. Furthermore, the sinterability was good. (C) 2001 Kluwer Academic Publis
hers.