Comparative photosensitised transformation of polychlorophenols with different sulphonated metallophthalocyanine complexes in aqueous medium

The relative efficiencies for the oxidation of trichlorophenol (TCP) and pe ntachlorophenol (PCP), sensitised by sulphonated phthalocyanine complexes c ontaining Zn, Al, Sn and Si as central metals, were studied in aqueous solu tions. For the first time, sulphonated silicon and tin phthalocyanines were synthesised and their activity towards photosensitisation of singlet oxyge n and photo-oxidation of polychlorophenols was examined. The efficiency of the sensitised photo-oxidative degradation of polychlorophenols depends not only on singlet oxygen quantum yield of sensitiser, but also on its stabil ity. The influence of substrate structure and the pH of the solution on the photo-oxidation efficiency, as well as on the sensitiser photodegradation were studied. It was found that the contribution of the Type II (singlet ox ygen-mediated) mechanism to the relative efficiency of the photosensitised photo-oxidation of the phenol, decreased from phenol top-chlorophenol, TCP and PCP, whereas Type I radical pathway increased. The results obtained for PCP give evidence that electron transfer from the excited sensitiser to th e substrate in its unionised form is responsible for enhanced sensitiser ph otodegradation. (C) 2001 Elsevier Science B.V. All rights reserved.