V. Sklyarchuk et Y. Plevachuk, Dynamics of the pseudogap transformation in semiconducting melts during metallization, J PHYS-COND, 13(41), 2001, pp. 9179-9185
Electrical conductivity sigma (T) and thermo-emf alpha (T) measurements, pe
rformed in a wide temperature range (from 700 to 1700 K) for binary S0.35Te
0.65 and ternary CuAsSe2 and TlASSe(2) liquid alloys, suggest that a transi
tion from semiconducting to metal conductivity occurs. The metallization te
mperature determined by thermo-emf measurements is lower than that determin
ed by electrical conductivity. A temperature-dependent transformation of th
e pseudogap width is interpreted in the frame of a screening mechanism of t
he bound states by the free electron gas in the pseudogap region.