New oscillatory process in aqueous solutions of compounds containing carbonyl and amino groups

Citation
Vl. Voeikov et al., New oscillatory process in aqueous solutions of compounds containing carbonyl and amino groups, KINET CATAL, 42(5), 2001, pp. 606-608
Citations number
10
Categorie Soggetti
Physical Chemistry/Chemical Physics","Chemical Engineering
Journal title
KINETICS AND CATALYSIS
ISSN journal
00231584 → ACNP
Volume
42
Issue
5
Year of publication
2001
Pages
606 - 608
Database
ISI
SICI code
0023-1584(200109/10)42:5<606:NOPIAS>2.0.ZU;2-3
Abstract
Frequency-correlated oscillations of chemiluminescence and the redox potent ial are observed during the amino-carbonyl reaction, which occurs in aqueou s solutions of methylglyoxal and various amino-containing compounds (ethano lamine, glycine, and beta -alanine) at room temperature. The duration and a mplitude of oscillations depend on the composition and concentration of the starting reactants, pH, stirring, and surface area through which oxygen di ffuses into the system.