The 18-crown-6-benzoyl peroxide-KBr supramolecular system in the initiation of homolytic chain-radical cumene oxidation

Authors
Opeida, IA Turovskii, NA Maksyuta, NV Pomeshchenko, AI
Citation
Ia. Opeida et al., The 18-crown-6-benzoyl peroxide-KBr supramolecular system in the initiation of homolytic chain-radical cumene oxidation, KINET CATAL, 42(5), 2001, pp. 613-614
Citations number
5
Categorie Soggetti
Physical Chemistry/Chemical Physics","Chemical Engineering
Journal title
KINETICS AND CATALYSIS
ISSN journal
00231584 → ACNP
Volume
42
Issue
5
Year of publication
2001
Pages
613 - 614
Database
ISI
SICI code
0023-1584(200109/10)42:5<613:T1PSSI>2.0.ZU;2-B
Abstract
The ability of the benzoyl peroxide-potassium bromide-18-crown-6 system to initiate the liquid-phase oxidation of cumene at 298 K was found. Individua l components of the initiating system. as well as the oxidation product (hy droperoxide), do not participate in the initiated oxidation reaction. The r ate of initiation was determined using the inhibitor method and by measurin g the initial rate of oxidation.