STUDY OF THE ROLE OF SODIUM HYPOPHOSPHITE IN ELECTROLESS NICKEL BATH SOLUTION

Citation
T. Mimani et Sm. Mayanna, STUDY OF THE ROLE OF SODIUM HYPOPHOSPHITE IN ELECTROLESS NICKEL BATH SOLUTION, Proceedings of the Indian Academy of Sciences. Chemical sciences, 109(3), 1997, pp. 203-209
Citations number
19
Categorie Soggetti
Chemistry
ISSN journal
02534134
Volume
109
Issue
3
Year of publication
1997
Pages
203 - 209
Database
ISI
SICI code
0253-4134(1997)109:3<203:SOTROS>2.0.ZU;2-D
Abstract
Cyclic voltametric investigations have been made to understand the ele ctrochemical behaviour of sodium hypophosphite in electroless plating bath solution. The possible reaction steps at the anode and cathode ha ve been identified. An ECE type of mechanism appears to be operative i n the overall reaction during electroless plating. Both organic and in organic species in the bath solution influence the voltammetric patter n of the hypophosphite. Temperature enhances the peak currents and cha nges the reaction mechanism. The oxidation potentials of the reaction steps vary with temperature and also the presence of organic component s in the bath solution.