A sample of 25 infrared-bright planetary nebulae (PNe) towards the Galactic
bulge is analysed through 8-13 mum spectroscopy. The classification of the
warm dust emission features provides a measure of the C/O chemical balance
, and represents the first C/O estimates for bulge PNe. Out of 13 PNe with
identified dust types, four PNe have emission features associated with C-ba
sed grains, while the remaining 9 have O-rich dust signatures. The low frac
tion of C-rich PNe, less than or similar to 30 per cent, contrasts with tha
t for local PNe, around similar to 80 per cent, although it follows the tre
nd for a decreasing frequency of C-rich PNe with galactocentric radius (Pap
er I). We investigate whether the PNe discussed here are linked to the bulg
e stellar population (similar to type IV, or halo, PNe) or the inner Galact
ic disc (a young and super-metal-rich population). Although 60 per cent of
the PNe with warm dust are convincing bulge members, none of the C-rich PNe
satisfies our criteria, and they are probably linked to the inner Galactic
disc. In the framework of single star evolution, the available information
on bulge PNe points towards a progenitor population similar in age to that
of local PNe (type I PNe are found in similar proportions), but super-meta
l-rich (to account for the scarcity of C-rich objects). Yet the metalliciti
es of bulge PNe, as inferred from [O/H], fail to reach the required values
- except for the C-rich objects. It is likely that the sample discussed her
e is derived from a mixed disc/bulge progenitor population and dominated by
type IV PNe, as suggested by Peimbert. The much higher fraction of O-rich
PNe in this sample than in the solar neighbourhood should result in a propo
rtionally greater injection of silicate grains into the inner Galactic medi
um.