Direct acetoacetylation of ferrocene and a 1,1 '-diphosphaferrocene

Authors
Plazuk, D Klys, A Zakrzewski, J Rybarczyk-Pirek, A Olszak, TA
Citation
D. Plazuk et al., Direct acetoacetylation of ferrocene and a 1,1 '-diphosphaferrocene, ORGANOMETAL, 20(22), 2001, pp. 4448-4450
Citations number
16
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
20
Issue
22
Year of publication
2001
Pages
4448 - 4450
Database
ISI
SICI code
0276-7333(20011029)20:22<4448:DAOFAA>2.0.ZU;2-I
Abstract
Reaction of ferrocene and 3,3',4,4'-tetramethyl-1,1'-diphosphaferrocene wit h diketene in the presence of BF3. Et2O affords the BF2 chelates of acetoac etylated metallocenes 2a,b. The crystal structures of these complexes have been determined by X-ray diffraction. When the reaction is carried out in t he presence of AlCl3, metallocene 1,3-diketones 3a,b are formed.