Four-, five-, and six-membered silaplatinacycles obtained from the reaction of an arylallene with Pt(SiHPh2)(2)(PMe3)(2)

Authors
Tanabe, M Yamazawa, H Osakada, K
Citation
M. Tanabe et al., Four-, five-, and six-membered silaplatinacycles obtained from the reaction of an arylallene with Pt(SiHPh2)(2)(PMe3)(2), ORGANOMETAL, 20(22), 2001, pp. 4451-4453
Citations number
32
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
20
Issue
22
Year of publication
2001
Pages
4451 - 4453
Database
ISI
SICI code
0276-7333(20011029)20:22<4451:FFASSO>2.0.ZU;2-V
Abstract
The reaction of (4-fluorophenyl)allene with Pt(SiHPh2)(2)(PMe3)(2) gives 2- sila-1-platinacyclobutane, 2,5-disila-1-platinacyclopentane, or 4-sila-1-pl atinacyclohexane, depending on the reaction conditions. All these complexes were characterized by X-ray crystallography and NMR spectroscopy.