Fluorous phase soluble palladium nanoparticles as recoverable catalysts for Suzuki cross-coupling and Heck reactions

Authors
Moreno-Manas, M Pleixats, R Villarroya, S
Citation
M. Moreno-manas et al., Fluorous phase soluble palladium nanoparticles as recoverable catalysts for Suzuki cross-coupling and Heck reactions, ORGANOMETAL, 20(22), 2001, pp. 4524-4528
Citations number
79
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
20
Issue
22
Year of publication
2001
Pages
4524 - 4528
Database
ISI
SICI code
0276-7333(20011029)20:22<4524:FPSPNA>2.0.ZU;2-7
Abstract
1,5-Bis(4,4'-bis(perfluorooctyl)phenyl)-1,4-pentadien-3-one stabilizes pall adium(0) nanoparticles (transmission electron microscopy) formed in the red uction of palladium dichloride with methanol. These palladium colloids are soluble in-perfluorinated solvents, and they are efficient recoverable cata lysts for Suzuki cross-couplings and Heck reactions under fluorous biphasic conditions.