Synthesis and molecular structure of a perfluoroalkyl complex of platinum containing a PCP pincer ligand

Authors
Hughes, RP Williamson, A Incarvito, CD Rheingold, AL
Citation
Rp. Hughes et al., Synthesis and molecular structure of a perfluoroalkyl complex of platinum containing a PCP pincer ligand, ORGANOMETAL, 20(22), 2001, pp. 4741-4744
Citations number
33
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
20
Issue
22
Year of publication
2001
Pages
4741 - 4744
Database
ISI
SICI code
0276-7333(20011029)20:22<4741:SAMSOA>2.0.ZU;2-U
Abstract
Treatment of (TMEDA)Pt(C3F7)Me (TMEDA = tetramethylethylenediamine) with 1, 3-bis[(diphenylphosphino)methyl]benzene (PCPH) in mesitylene under reflux a ffords the first known pincer complex of a group 10 metal with a fluoroalky l ligand.