The effect of cooling rate on the density of the Pd40Ni10Cu30P20 bulk metal
lic glass (BMG) have been investigated by over the cooling rate range from
0.63 to 500 K/s. The cooling rate dependence of density, microhardness and
thermal properties of the BMG is determined. Based on the thermal-expansion
coefficients measured in the amorphous and supercooled liquid states, resp
ectively, it is deduced that the density of the BMG in the "ideal" state ap
proaches that of its crystalline counterpart. The effect of cooling rate on
the density is discussed in terms of structural relaxation.