The sintering behaviour of high carbon-high vanadium water atomised M35MHV
HSS (1(.)8 wt-%C, 4(.)2 wt-%V) is analysed as a function of the nitrogen pr
essure in the sintering atmosphere. Uniaxially pressed compacts were sinter
ed to full density (greater than or equal to 98%TD) under different N-2 atm
ospheres in a range of pressures from vacuum to 8 bar. It is observed that
the optimum sintering temperature (OST) depends on the absorbed nitrogen an
d is as low as 1050 degreesC when the nitrogen content in the steel is 1(.)
2 wt-%. The absorbed nitrogen affects not only the OST but also the matrix
and carbides composition and the phases present after sintering. Compared w
ith other powders processed under the same conditions, it is shown that the
amount of absorbed nitrogen depends not only on the nitrogen partial press
ure in the sintering atmosphere but also on the amount of vanadium and carb
on and even on the heating rate. Hardness, fracture toughness, and fracture
strength values are reported after heat treatment. (C) 2001 IoM Communicat
ions Ltd.