J. Karwan-baczewska et M. Rosso, Effect of boron on microstructure and mechanical properties of PM sinteredand nitrided steels, POWD METALL, 44(3), 2001, pp. 221-227
PM Distaloy and Astaloy alloys have many applications in the automotive ind
ustry and are used in structural elements with different wear resistance va
lues. Their main features are adequate density, hardness, tensile strength,
and good ductility. For the purpose of the experiment presented here, Dist
aloy SA and Astaloy Mo powders, alloyed with various amounts of elemental b
oron powder, were used. The Distaloy and Astaloy alloys were produced throu
gh mixing, compacting, and sintering at t = 1393 and 1473 K, and, after the
completed sintering process, they were plasma nitrided at 793 K. Experimen
tal results showed that if boron was added, while sintering, the shrinkage
phenomena increased ( 1473 K) and some parameters of those alloys (density,
hardness, and tensile strength) were improved. Upon the ion nitriding trea
tment of the surface of base Astaloy Mo samples, a surface layer was create
d composed of the E solution and gamma' nitride, whereas the surface layer
on the Distaloy SA base was mainly composed of a gamma' compound. Boron act
ivates the sintering process of Distaloy SA and Astaloy Mo samples but it h
as no significant impact on the surface layer's thickness of Distaloy SA al
loys as opposed to Astaloy Mo alloys in which boron promotes a greater thic
kness of surface layers along with a reduced depth of nitrogen diffusion. (
C) 2001 IoM Communications Ltd.