The present review describes some of our recent applications of tricarbonyl
irondiene chemistry to organic synthesis. It focuses on the selective synth
esis of tricarbonylirondiene complexes including the asymmetric catalytic c
omplexation of prochiral cyclohexa-1,3-dienes, the enantioselective synthes
is of carbazole-3,4-quinone alkaloids, and the iron-mediated synthesis of c
orannulene and yohimbane alkaloids.