Identification of intermediates in the reaction of 2-thenyl halides with magnesium

Authors
Egorov, AM Kuznetsova, SV Anisimov, AV
Citation
Am. Egorov et al., Identification of intermediates in the reaction of 2-thenyl halides with magnesium, RUSS CHEM B, 49(9), 2000, pp. 1544-1547
Citations number
19
Categorie Soggetti
Chemistry
Journal title
RUSSIAN CHEMICAL BULLETIN
ISSN journal
10665285 → ACNP
Volume
49
Issue
9
Year of publication
2000
Pages
1544 - 1547
Database
ISI
SICI code
1066-5285(200009)49:9<1544:IOIITR>2.0.ZU;2-3
Abstract
The reaction of 2-thenyl chloride with magnesium was shown by the ESR metho d to proceed via the intermediate formation of radicals and radical ion pai rs, whereas similar reactions of 2-thenyl bromide and iodide occur through the formation of free radicals only.