New approach to cyclic sulfites and sulfates through reactions of sulfur oxychlorides with glycidols

Authors
Bredikhin, AA Pashagin, AV Bredikhina, ZA Lazarev, SN Gubaidullin, AT Litvinov, IA
Citation
Aa. Bredikhin et al., New approach to cyclic sulfites and sulfates through reactions of sulfur oxychlorides with glycidols, RUSS CHEM B, 49(9), 2000, pp. 1575-1582
Citations number
25
Categorie Soggetti
Chemistry
Journal title
RUSSIAN CHEMICAL BULLETIN
ISSN journal
10665285 → ACNP
Volume
49
Issue
9
Year of publication
2000
Pages
1575 - 1582
Database
ISI
SICI code
1066-5285(200009)49:9<1575:NATCSA>2.0.ZU;2-F
Abstract
Reactions of 2,3-epoxyalcohols (glycidols) with thionyl chloride or sulfury l chloride afford cyclic sulfites or sulfates, respectively. These reaction s yield predominantly 4-chloroalkyl-1,3,2-dioxathiolane oxides. The configu ration of the C(4) atom in the latter compounds exactly corresponds to that of the C(2) atom of the parent glycidol, whereas the configuration of the exocyclic atom is almost completely reversed with respect to that of the C( 3) atom of the precursor.