Electrophilic substitution reactions of ferracarborane 3-(eta(5)-Cp)-4-SMe2-3,1,2-FeC2B9H10

Authors
Timofeev, SV Lobanova, IA Kudinov, AR Meshcheryakov, VI Tok, OL Petrovskii, PV Dolgushin, FM Starikova, ZA Bregadze, VI
Citation
Sv. Timofeev et al., Electrophilic substitution reactions of ferracarborane 3-(eta(5)-Cp)-4-SMe2-3,1,2-FeC2B9H10, RUSS CHEM B, 49(9), 2000, pp. 1598-1604
Citations number
14
Categorie Soggetti
Chemistry
Journal title
RUSSIAN CHEMICAL BULLETIN
ISSN journal
10665285 → ACNP
Volume
49
Issue
9
Year of publication
2000
Pages
1598 - 1604
Database
ISI
SICI code
1066-5285(200009)49:9<1598:ESROF3>2.0.ZU;2-Z
Abstract
Mercuration and bromination reactions of ferracarborane 3-(eta (5)-Cp)-4-SM e2-3,1,2-FeC2B9H10 (1) were investigated. Mercuration of 1 under mild condi tions (mercury trifluoroacetate in dichloromethane) results in 8-monosubsti tuted mercury derivative as the only reaction product. Depending on the rea ction conditions, bromination of 1 results in 8-mono- or 7,8-disubstituted bromo derivatives. The structures of the monomercury and dibromo derivative s of 1 were established by X-ray analysis.