"Anhydrolycaconitine," a new diterpene alkaloid from Aconitum septentrionale K.

Citation
Ms. Yunusov et al., "Anhydrolycaconitine," a new diterpene alkaloid from Aconitum septentrionale K., RUSS CHEM B, 49(9), 2000, pp. 1629-1633
Citations number
17
Categorie Soggetti
Chemistry
Journal title
RUSSIAN CHEMICAL BULLETIN
ISSN journal
10665285 → ACNP
Volume
49
Issue
9
Year of publication
2000
Pages
1629 - 1633
Database
ISI
SICI code
1066-5285(200009)49:9<1629:"ANDAF>2.0.ZU;2-H
Abstract
A new alkaloid, anhydrolycaconitine (C36H46N2O9), was isolated from roots o f Aconitum septentrionale K. Based on the results of H-1 and C-13 NMR and I R spectroscopy and mass spectrometry of the alkaloid and the product of its alkaline hydrolysis and on the data of X-ray diffraction analysis of the h ydrolysis product, the structure of 1 alpha ,6 beta ,14 alpha ,16 beta -tet ramethoxy-7-oxo-18-succinylanthranoyloxy-17-(7 -->8)abeo-aconane was assign ed to anhydrolycaconitine.