Kinetic features of the reaction of alpha-oxide groups of hydrated cellulose-polyglycidyl methacrylate graft copolymers with thiourea and potassium thiocyanate

Citation
Tv. Druzhinina et al., Kinetic features of the reaction of alpha-oxide groups of hydrated cellulose-polyglycidyl methacrylate graft copolymers with thiourea and potassium thiocyanate, RUS J AP CH, 73(4), 2000, pp. 689-693
Citations number
9
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF APPLIED CHEMISTRY
ISSN journal
10704272 → ACNP
Volume
73
Issue
4
Year of publication
2000
Pages
689 - 693
Database
ISI
SICI code
1070-4272(200004)73:4<689:KFOTRO>2.0.ZU;2-Y
Abstract
The kinetics of heterophase macromolecular reaction of a-oxide groups of hy drated cellulose-polyglycidyl methacrylate graft copolymer with thiourea an d potassium thiocyanate were studied. Mathematical equations describing thi s process were obtained using the modified quasistationary procedure. A cor relation between the chemical structure of graft copolymer and the degree o f conversion of polyglycidyl methacrylate was established.