Deuterium fluoride synthesis in the system D-2-AgF2-ClF3

Authors
Parbuzin, VS Sukhoverkhov, VF Yakovlev, VA
Citation
Vs. Parbuzin et al., Deuterium fluoride synthesis in the system D-2-AgF2-ClF3, RUSS J IN C, 46(10), 2001, pp. 1466-1468
Citations number
4
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
ISSN journal
00360236 → ACNP
Volume
46
Issue
10
Year of publication
2001
Pages
1466 - 1468
Database
ISI
SICI code
0036-0236(200110)46:10<1466:DFSITS>2.0.ZU;2-C
Abstract
Two pathways to obtaining deuterium fluoride in the system D-2-AgF2-CIF3 th at exclude direct con-tact of D-2 with CIF3 are investigated: (1) DF synthe sis by the action of D-2 on AgF2 and AgF2 regeneration by the action of CIF 3 on Ag and (2) a three-stage synthesis simultaneously producing two deuter ium halides (DF + DC1). The two-stage process is recommended as a convenien t route to obtain DF of high chemical and isotopic (99% D) purity on a labo ratory scale from commercially available reagents.