Solid-phase synthesis of copper(II) beta-diketonates upon mechanical activation

Authors
Petrova, LA Borisov, AP Aleshin, VV Makhaev, VD
Citation
La. Petrova et al., Solid-phase synthesis of copper(II) beta-diketonates upon mechanical activation, RUSS J IN C, 46(10), 2001, pp. 1501-1506
Citations number
22
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
ISSN journal
00360236 → ACNP
Volume
46
Issue
10
Year of publication
2001
Pages
1501 - 1506
Database
ISI
SICI code
0036-0236(200110)46:10<1501:SSOCBU>2.0.ZU;2-E
Abstract
We showed that a solid-state reaction of copper(III) chloride with sodium b eta -diketonates upon mechanical treatment in a vibration ball mill results in copper(H) beta -diketonates. The influence of milling conditions and th e nature of the reactants an the course of the process, product yield, and some properties of activated mixtures was studied. The yield of copper(II) beta -diketonates reaches 70-90%. After mechanical preactivation of the rea ction mixture, copper(II) beta -diketonate synthesis can proceed as a self- propagating reaction.