The paper investigates the formation of in situ TiB2 via a chemical reactio
n among Al, TiO2 and B2O3. Thermodynamic assessment shows the formation of
TiB2 through two stages, namely, reduction of Ti and B from their oxides fo
llowed by formation of TiB2. 53% and 44% increases in the yield and ultimat
e tensile stresses of the composite reinforced with 15%TiB2 compared to its
unreinforced counterpart have been observed. (C) 2001 Acta Materialia Inc.
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