InCl3-SiO2 catalyzed electrophilic amination of arenes: A facile and rapidsynthesis of aryl hydrazides

Citation
Js. Yadav et al., InCl3-SiO2 catalyzed electrophilic amination of arenes: A facile and rapidsynthesis of aryl hydrazides, SYNLETT, (11), 2001, pp. 1781-1783
Citations number
17
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNLETT
ISSN journal
09365214 → ACNP
Issue
11
Year of publication
2001
Pages
1781 - 1783
Database
ISI
SICI code
0936-5214(200111):11<1781:ICEAOA>2.0.ZU;2-D
Abstract
Electron-rich arenes undergo electrophilic amination with diethyl azodicarb oxylate on the surface of silica gel impregnated with indium trichloride in solvent-free conditions to afford parasubstituted aryl hydrazides. Improve d yields and enhanced rates are obtained by employing microwave irradiation .