Determination and speciation of aluminum in environmental samples by cation exchange high-performance liquid chromatography with high resolution ICP-MS detection

Citation
Ki. Tsunoda et al., Determination and speciation of aluminum in environmental samples by cation exchange high-performance liquid chromatography with high resolution ICP-MS detection, WATER A S P, 130(1-4), 2001, pp. 1589-1594
Citations number
13
Categorie Soggetti
Environment/Ecology
Journal title
WATER AIR AND SOIL POLLUTION
ISSN journal
00496979 → ACNP
Volume
130
Issue
1-4
Year of publication
2001
Part
3
Pages
1589 - 1594
Database
ISI
SICI code
0049-6979(200108/09)130:1-4<1589:DASOAI>2.0.ZU;2-#
Abstract
A cation-exchange high-performance liquid chromatography with high resoluti on inductively coupled plasma mass spectrometric detection (CE-HPLC/ICP-MS) was developed for the determination and the speciation of aluminum in envi ronmental samples. Three types of aluminum species (AlLx< +2, AlLx2+, Al3+) were separated from one another, and were determined with the present syst em. The comparison of the present system with an established CE-HPLC with f luorimetric detection using 5-sulfo-8-quinolinol (CE-HPLC/FL) was described . The present system showed better sensitivity for aluminum than CE-HPLC/FL . Moreover, the analytical results for soil extract and lake water samples obtained with both methods were in good agreement with each other.