THERMODYNAMICAL ANALYSIS OF NONSTOICHIOMETRIC THALLIUM OXIDES AND REACTIVITY PREDICTION FOR ELECTROSYNTHESIS

Authors
TSIRLINA GA SAFONOVA OV PETRII OA
Citation
Ga. Tsirlina et al., THERMODYNAMICAL ANALYSIS OF NONSTOICHIOMETRIC THALLIUM OXIDES AND REACTIVITY PREDICTION FOR ELECTROSYNTHESIS, Electrochimica acta, 42(19), 1997, pp. 2943-2946
Citations number
14
Categorie Soggetti
Electrochemistry
Journal title
Electrochimica acta → ACNP
ISSN journal
00134686
Volume
42
Issue
19
Year of publication
1997
Pages
2943 - 2946
Database
ISI
SICI code
0013-4686(1997)42:19<2943:TAONTO>2.0.ZU;2-T
Abstract
An approach is proposed for the simulation of potential-pH diagrams wh ich takes into account deviations of oxide composition from stoichiome try. The model of regular solid solution is used for the analysis of e lectrochemical thermodynamics of thallous ion (oxide)-thallic oxide-th allium superoxide (peroxide) system. Potential values corresponding to certain compositions of the product of Tl2O3 anodic oxidation are pre dicted. (C) 1997 Published by Elsevier Science Ltd.