A three-dimensional porous framework complex, poly[[bis(ethylenediamine)copper(II)] [potassium hexacyanocobalt(III)]]

Authors
Li, BL Shen, XP Zou, JZ Xu, Z Yu, KB
Citation
Bl. Li et al., A three-dimensional porous framework complex, poly[[bis(ethylenediamine)copper(II)] [potassium hexacyanocobalt(III)]], ACT CRYST C, 57, 2001, pp. 1242-1244
Citations number
14
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
57
Year of publication
2001
Part
11
Pages
1242 - 1244
Database
ISI
SICI code
0108-2701(200111)57:<1242:ATPFCP>2.0.ZU;2-E
Abstract
The crystal structure of the title compound, {[Cu(en)(2)][K-Co(CN)(6)]}(n) (en is ethylenediamine, C2H8N2), reveals a novel three-dimensional porous f ramework in which [Cu(en)(2)](2+) acts as a template and K+ as a connecting unit. The Cu atom lies on an inversion centre and the Co and K atoms are o n twofold axes.