Potassium bis(4,5-dimercapto-1,3-dithiole-2-thionato)nickelate 1,4,7,10,13,16-hexaoxa-2,3 : 11,12-dibenzocyclooctadeca-2,11-diene propanone solvate

Authors
Shitagami, K Akutagawa, T Hasegawa, T Nakamura, T Robertson, N
Citation
K. Shitagami et al., Potassium bis(4,5-dimercapto-1,3-dithiole-2-thionato)nickelate 1,4,7,10,13,16-hexaoxa-2,3 : 11,12-dibenzocyclooctadeca-2,11-diene propanone solvate, ACT CRYST C, 57, 2001, pp. 1271-1273
Citations number
13
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
57
Year of publication
2001
Part
11
Pages
1271 - 1273
Database
ISI
SICI code
0108-2701(200111)57:<1271:PB1>2.0.ZU;2-X
Abstract
In the title compound, K[Ni(C3S5)(2)]C20H24O6 .C3H6O, K+ is incorporated in the cavity of the 1,4,7,10,13,16-hexaoxa-2,3:11,12-dibenzocyclooctadeca-2, 11-diene (DB18c6) molecule and is coordinated by the six DB18c6 O atoms and the propanone O atom. Two {K+ (DB18c6)[(CH3)(2) CO]} units form a dimer wh ich is aligned in a one-dimensional manner along the a axis through a face- to-face interaction between the benzene rings of neighboring DB18c6 molecul es. [Ni(dmit)(2)](-) anions are also aligned along the a axis through side- by-side S . . .S interactions.