P. Tartaj et al., Single-step nanoengineering of silica coated maghemite hollow spheres withtunable magnetic properties, ADVAN MATER, 13(21), 2001, pp. 1620
Tunable magnetic hollow spheres of gamma -Fe2O3 with a silica-enriched surf
ace layer have been synthesized by aerosol pyrolysis of an iron ammonium ci
trate/TEOS solution in methanol. Careful temperature control is crucial for
an optimum yield of intact spheres. The Figure shows a TEM image of a sphe
re, revealing the outer layer consisting mainly of silica. The material is
potentially interesting for magnetic-fluid applications, e.g., in medicine.