SYNTHESIS OF NOVEL DIAMAGNETIC CHROMIUM(II) ALKYL COMPLEXES

Authors
KUZELKA J LEGZDINS P RETTIG SJ SMITH KM
Citation
J. Kuzelka et al., SYNTHESIS OF NOVEL DIAMAGNETIC CHROMIUM(II) ALKYL COMPLEXES, Organometallics, 16(16), 1997, pp. 3569-3571
Citations number
38
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
16
Issue
16
Year of publication
1997
Pages
3569 - 3571
Database
ISI
SICI code
0276-7333(1997)16:16<3569:SONDCA>2.0.ZU;2-Z
Abstract
Reaction of Cr(NO)((NPr2)-Pr-i)(3) with PhCO2H leads to Cr(NO)((NPr2)- Pr-i)(O2CPh)(2) (1). The benzoate ligands of 1 may be replaced to form the diamagnetic, structurally-characterized organometallic complexes CpCr(NO)-((NPr2)-Pr-i)(OC(O)Ph) (2), CpCr(NO)((NPr2)-Pr-i)(CH2SiMe3) ( 3),and Cr(NO)((NPr2)-Pr-i)(CH2SiMe3)(2) (4).