CONVENIENT SYNTHESIS OF W(CR)X-3(DME) COMPOUNDS FROM W(CR)(OBUT)(3) TRIPLE-BOND METATHESIS PRODUCTS

Authors
STEVENSON MA HOPKINS MD
Citation
Ma. Stevenson et Md. Hopkins, CONVENIENT SYNTHESIS OF W(CR)X-3(DME) COMPOUNDS FROM W(CR)(OBUT)(3) TRIPLE-BOND METATHESIS PRODUCTS, Organometallics, 16(16), 1997, pp. 3572-3573
Citations number
48
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
16
Issue
16
Year of publication
1997
Pages
3572 - 3573
Database
ISI
SICI code
0276-7333(1997)16:16<3572:CSOWCF>2.0.ZU;2-7
Abstract
Tungsten-alkylidyne complexes of the type W(drop CR)X-3(dme) (R = Bu-t , Pr-n, Ph; X = Cl, Br; dme = 1,2-dimethoxyethan) are prepared in 77-8 7% yields from reactions between W(drop CR)(OBut)(3) and BX3 in the pr esence of dime.